| Time | Court | Player |
| 12.30pm | 23 | Elina Svitolina, Kristina Mladenovic |
| 12.30pm | 26 | Aleksandra Krunic |
| 1.00pm | 30 | Jaimee Fourlis, Olivia Rogowska |
| 1.30pm | 21 | Dominic Thiem, Sergiy Stakhovsky |
| 1.30pm | 25 | Jason Kubler, Akira Santillan |
| 1.30pm | 27 | Destanee Aiava, Harriet Dart |
| 2.00pm | 21 | Amanda Anisimova |
| 2.00pm | 26 | Whitney Osuigwe |
| 2.00pm | 27 | Nicole Gibbs, Ana Bogdan |
| 2.00pm | 29 | Jelena Ostapenko |
| 3.00pm | 29 | Carla Suarez Navarro |
| 3.00pm | 30 | Viktor Troicki |
| 4.00pm | 25 | Dusan Lajovic, Nenad Zimonjic |
| 5.00pm | 24 | Venus Williams |
| 5.00pm | 28 | Borna Coric |
| 5.00pm | 30 | Horia Tecau, Jean-Julien Rojer |
| 6.00pm | 21 | Marin Cilic |
| 6.00pm | 23 | Fernando Verdasco |